{"id":10,"date":"2014-07-01T07:49:03","date_gmt":"2014-07-01T07:49:03","guid":{"rendered":"http:\/\/blogs.cardiff.ac.uk\/wirth\/?page_id=10"},"modified":"2026-09-03T13:33:37","modified_gmt":"2026-09-03T13:33:37","slug":"publications","status":"publish","type":"page","link":"https:\/\/blogs.cardiff.ac.uk\/wirth\/publications\/","title":{"rendered":"Publications 2025\u20132026"},"content":{"rendered":"<h1>2025<\/h1>\n<p><strong>306. Hydrofluoroether Synthesis through One-Pot Anodic Iodoalkoxylation of Alkenes<\/strong><br \/>\nM. Becerra-Ruiz, B. Winterson, E. G. P\u00e9rez, T. Wirth,\u00a0<em>Adv. Synth. Catal.\u00a0<\/em><strong>2025<\/strong>,\u00a0<em>367<\/em>, e202401108. <a href=\"https:\/\/doi.org\/10.1002\/adsc.202401108\">DOI<\/a><\/p>\n<p><strong>307. B(C<small>6<\/small>F<small>5<\/small>)<small>3<\/small> Catalyzed Regiodivergent Thioetherifications of Alkenes via Thiiranium Intermediates: Experimental and Computational Insights<\/strong><br \/>\nN. Alotaibi, R. Babaahmadi, S. Das, E. Richards, M. Pramanik, T. Wirth, R. L. Melen, <em>Chem. Eur. J. <\/em><strong>2025<\/strong>, <i>31<\/i>, e202404236. <a href=\"https:\/\/doi.org\/10.1002\/chem.202404236\">DOI<\/a><\/p>\n<p><strong>308. Raman Study of Intermediates Formed During the Electrochemical <em>N<\/em>-Nitrosation of Secondary Amines<\/strong><br \/>\nS. Richardson, R. Babaahmadi, L. Edwards, R. Ali, R. L. Melen, D. Roy, T. Wirth, <em>Chem. Meth. <\/em><strong>2025<\/strong>, <i>5<\/i>, e202400067. <a href=\"https:\/\/doi.org\/10.1002\/cmtd.202400067\">DOI<\/a><\/p>\n<p><strong>309. Synthesis and Reactivity of Six-Membered Cyclic Diaryl \u03bb<small>3<\/small>-Bromanes and \u03bb<small>3<\/small>-Chloranes<\/strong><br \/>\nD. Bhattacherjee, B. M. Kariuki, B. A. Piscelli, R. A. Cormanich, T. Wirth, <em>Angew. <\/em><em>Chem. Int. Ed. <\/em><strong>2025<\/strong>, <em>64<\/em>, e202424559. <a href=\"https:\/\/doi.org\/10.1002\/anie.202424559\">DOI<\/a><\/p>\n<p><strong><span dir=\"ltr\" role=\"presentation\">\u00a0 \u00a0 \u00a0 Synthese und Reaktivit\u00e4t sechsgliedriger zyklischer Diaryl<\/span> <span dir=\"ltr\" role=\"presentation\">\u03bb<small>3<\/small><\/span><span dir=\"ltr\" role=\"presentation\">&#8211;<\/span><\/strong><strong><span dir=\"ltr\" role=\"presentation\">Bromane und<\/span> <span dir=\"ltr\" role=\"presentation\">\u03bb<small>3-<\/small><\/span><span dir=\"ltr\">Chlorane<br \/>\n<\/span><\/strong><span dir=\"ltr\">\u00a0 \u00a0 \u00a0 D. Bhattacherjee, B. M. Kariuki, B. A. Piscelli, R. A. Cormanich, T. Wirth, <\/span><span dir=\"ltr\"><em>Angew. <\/em><\/span><span dir=\"ltr\"><em>Chem. <\/em><\/span><span dir=\"ltr\"><strong>2025<\/strong>, <em>137<\/em>, e202424559<i>.<\/i><\/span>\u00a0<a href=\"https:\/\/doi.org\/10.1002\/ange.202424559\">DOI<\/a><\/p>\n<p><strong>310. Electrochemical Fluorination of Proline Derivatives<\/strong><br \/>\nP. Ryan, D. Bhattacherjee, T. Wirth, L. Hunter, G. Pascali,\u00a0<em>Eur. J. Org. Chem. <\/em><strong>2025<\/strong>,<em> 28<\/em>, e202500264. <a href=\"https:\/\/doi.org\/10.1002\/ejoc.202500264\">DOI<\/a><\/p>\n<p><strong>311. Electrolyte-Controlled Regiodivergent Continuous Flow Electroselenocyclisations<\/strong><br \/>\n<span dir=\"ltr\">S. Arepally, H. Gieman, T. Wirth<\/span>, <em>Angew. <\/em><em>Chem. Int. Ed. <\/em><strong>2025<\/strong>, <em>64<\/em>, e202509811. <a href=\"https:\/\/doi.org\/10.1002\/anie.202509811\">DOI<\/a><\/p>\n<p><strong><span dir=\"ltr\" role=\"presentation\">\u00a0 \u00a0 Elektrolytgesteuerte, regiodivergente, kontinuierliche Elektroselenozyklisierungen<\/span><\/strong><strong><span dir=\"ltr\"><br \/>\n<\/span><\/strong><span dir=\"ltr\">\u00a0 \u00a0 \u00a0 S. Arepally, H. Gieman, T. Wirth, <\/span><span dir=\"ltr\"><em>Angew. <\/em><\/span><span dir=\"ltr\"><em>Chem. <\/em><\/span><span dir=\"ltr\"><strong>2025<\/strong>, <em>137<\/em>, e202509811<i>.<\/i><\/span>\u00a0<a href=\"https:\/\/doi.org\/10.1002\/ange.202509811\">DOI<\/a><\/p>\n<p><strong>312. Flow electrochemical oxidation of <i>N<\/i>-nitrosamines to <i>N<\/i>-nitramines<\/strong><br \/>\nR. Ali, K. Matsui, J. \u0160adauskis, A. Catherall, T. Wirth, <em>Chem. Commun. <\/em><strong>2025<\/strong>, <em>61<\/em>, 13671\u201313674. <a href=\"https:\/\/doi.org\/10.1039\/D5CC03458B\">DOI<\/a><\/p>\n<p><strong>313. Imidazopyridine substituted cyclic selenonium(IV) salts as chalcogen bond catalyst<\/strong><br \/>\nT. Kuzmera, P. Puylaert, T. Wirth, B. J. Nachtsheim, <em>Chem. Commun. <\/em><strong>2025<\/strong>, <em>61<\/em>, 14169\u201314172. <a href=\"https:\/\/doi.org\/10.1039\/D5CC04027B\">DOI<\/a><\/p>\n<p><strong>314. Electrochemical \u237a-C\u2013H Functionalization of Nitramines for Accessing Bifunctional Energetic Heterocycles<\/strong><br \/>\nW.-C. C. Lee, L. F. T. Novaes, R. Ali, T. Wirth, S. Lin, <em>Angew. Chem. Int. Ed. <\/em><strong>2025<\/strong>, <em>64<\/em>, e202515252. <a href=\"https:\/\/doi.org\/10.1002\/anie.202515252\">DOI<\/a><\/p>\n<p><strong>315. Electric-Field-Assisted Organic Synthesis: A New Frontier in Reactivity Control<\/strong><br \/>\nH. Chadwick, G. Cocking, J. Westph\u00e4ling, R. L. Melen, T. Wirth,\u00a0<em>SynOpen <\/em><strong>2025<\/strong>, <em>9<\/em>, 282\u2013291. <a href=\"https:\/\/doi.org\/10.1055\/a-2744-2506\">DOI<\/a><\/p>\n<h1>2026<\/h1>\n<p><strong>316. Oxidative Rearrangement of Alkynes to chiral \u03b1-Arylalkanoic Esters<br \/>\n<\/strong>R. Alkahtani, J. Westph\u00e4ling, A. Gorecka, R. Babaahmadi, H. Gieman, M. Finance, J. Lorente Martinez, D. Bhattacherjee, R. L. Melen, M.-H. Baik, T. Wirth,\u00a0<em>Chem. Sci.\u00a0<\/em><strong>2026<\/strong>, <em>17<\/em>, 1318\u20131324. <a href=\"https:\/\/doi.org\/10.1039\/D5SC07882B\">DOI<\/a><\/p>\n<p><strong>317. Thiol-Free Sulfenylation Redefined: A Single-Atom Transfer Pathway to Symmetrical Di(hetero)arylthioethers via B(C<span dir=\"ltr\" role=\"presentation\"><small>6<\/small><\/span>F<span dir=\"ltr\" role=\"presentation\"><small>5<\/small><\/span>)<span dir=\"ltr\" role=\"presentation\"><small>3<\/small><\/span> Catalysis<br \/>\n<\/strong>M. Pramanik, N. Alotaibi, T. Boruah, N. J. Buurma, R. Babaahmadi, T. Wirth, R. L. Melen,\u00a0<em>J. Am. Chem. Soc.\u00a0<\/em><strong>2026<\/strong>, <em>148<\/em>, 5325\u20135337. <a href=\"https:\/\/doi.org\/10.1021\/jacs.5c17932\">DOI<\/a><\/p>\n<p><strong>318. Revealing the Mechanism of TEMPO-Hypervalent Iodine(III) Oxidation of Alcohols<br \/>\n<\/strong>M. Bingham, T. R. Pradhan, D. Bhattacherjee, R. Alkahtani, P. Kavanagh, T. Wirth, P. Dingwall, <em>J. Am. Chem. Soc.\u00a0<\/em><strong>2026<\/strong>, <em>148<\/em>, 8852\u20138862. <a href=\"https:\/\/doi.org\/10.1021\/jacs.5c21609\">DOI<\/a><strong><br \/>\n<\/strong><\/p>\n<p><strong>319. Electrochemical Regioselective Chalcogenocyclizations of 2-Alkynylbenzamides in Flow<\/strong><br \/>\n<span dir=\"ltr\">H. Gieman,\u00a0<\/span><span style=\"font-size: 14.000001px\">S. Arepally,<\/span><span style=\"font-size: 14.000001px\">\u00a0<\/span><span dir=\"ltr\" style=\"font-size: 1rem\">T. Wirth<\/span><span style=\"font-size: 1rem\">,\u00a0<em>ChemElectroChem\u00a0<\/em><strong>2026<\/strong>,\u00a0<em>13<\/em>, e202500471. <a href=\"http:\/\/dx.doi.org\/10.1002\/celc.202500471\">DOI<\/a><\/span><\/p>\n<p><strong>320<\/strong><strong>. Synthesis and Structure of Group 13 POCOP Complexes<br \/>\n<\/strong>S. Pahar, T. Wilde, K. Agrawal, N. T. Coles, B. M. Kariuki, D. L. Kays, A. J. Logsdail, T. Wirth, E. Richards, R. L. Melen, <em>Inorg. Chem.<\/em> <strong>2026<\/strong>, <em>65<\/em>, 8289\u20138300. <a href=\"https:\/\/doi.org\/10.1021\/acs.inorgchem.5c05278\">DOI<\/a><\/p>\n<p><strong>321. Borane Catalysed Annulative Sulfenylation of Internal Alkynes: Towards the Synthesis and Study of Highly Unsaturated Heterocycles<br \/>\n<\/strong>S. Das, M. Pramanik, J. Westph\u00e4ling, A. K. Gupta, T. Wirth, E. Zysman-Colman, N. J. Buurma, M.-H. Baik, R. L. Melen, <em>Chem. Sci.\u00a0<\/em><strong>2026<\/strong>, <em>17<\/em>, 11682\u201311692.\u00a0<a href=\"https:\/\/doi.org\/10.1039\/D6SC01123C\">DOI<\/a><\/p>\n<p><strong>322. Numbering-Up Flow Electroreduction of \u03b1,\u03b2-Unsaturated Carbonyls from Gram to Pilot-Relevant Scale<br \/>\n<\/strong><span style=\"font-size: 14.000001px\">T. Boruah, S. Arepally, R. L. Melen, <\/span><span dir=\"ltr\" style=\"font-size: 1rem\">T. Wirth<\/span><span style=\"font-size: 1rem\">,\u00a0<em>Org. Process Res. Dev. <\/em><strong>2026<\/strong>, <em>30<\/em>, 2067\u20132074. <a href=\"https:\/\/doi.org\/10.1021\/acs.oprd.6c00175\">DOI<\/a><\/span><strong><br \/>\n<\/strong><\/p>\n<p><strong>323. Hydrogen bonding interactions in HFIP enabling the cascade synthesis of sulfenylated 2<em>H<\/em>-chromenes<\/strong><br \/>\nD. H.-P. Mak, S. Das, J. Westph\u00e4ling, T. \u00a0Jeans, A. Gorecka, T. Wirth, M. Pramanik, M.-H. Baik, R. L. Melen, <em>Chem. Commun. <\/em><strong>2026<\/strong>,\u00a0<em>62<\/em>, 14821\u201314825<em>.\u00a0<\/em><a href=\"https:\/\/doi.org\/10.1039\/d6cc02791a\">DOI<\/a><\/p>\n<p><strong>324. Oxidative Flow Electrochemistry: A Platform for Generating Reactive Intermediates and Reaction Control<br \/>\n<\/strong><span style=\"font-size: 14.000001px\">S. Arepally, T. Boruah, R. L. Melen, <\/span><span dir=\"ltr\" style=\"font-size: 1rem\">T. Wirth<\/span><span style=\"font-size: 1rem\">,\u00a0<em>Acc. Chem. Res. <\/em><strong>2026<\/strong>, <em>59,<\/em>\u00a02800\u20132815. <a href=\"https:\/\/doi.org\/10.1021\/acs.accounts.6c00413\">DOI<\/a><\/span><\/p>\n<p><strong>325. Continuous Flow Electrochemical Oxidation of Activated Methylarenes Using O<span dir=\"ltr\" role=\"presentation\"><small>2<br \/>\n<\/small><\/span><\/strong><span dir=\"ltr\" role=\"presentation\"><small><span style=\"font-size: 14.000001px\">N. Alqahtani, S. Iwai, T. Boruah, R. L. Melen, <\/span><\/small><\/span><span dir=\"ltr\" role=\"presentation\"><small><span dir=\"ltr\" style=\"font-size: 1rem\">T. Wirth<\/span><\/small><\/span><span dir=\"ltr\" role=\"presentation\"><small><span style=\"font-size: 1rem\">,\u00a0<em>Org. Biomol. Chem.<\/em> <strong>2026<\/strong>, <em>24<\/em>, 6754\u20136758. <a href=\"https:\/\/doi.org\/10.1039\/D6OB01129B\">DOI<\/a><\/span><\/small><\/span><strong><span dir=\"ltr\" role=\"presentation\"><small><br \/>\n<\/small><\/span><\/strong><\/p>\n<p><strong>326. Condensing the Cage: Novel Insights into the Reaction Pathway of Isowurtzitane Cage Formation<\/strong><br \/>\nC. S. Wolfe, P. F. N. Stewart, R. M. Campbell, J. R. White, A. M. Beardah,\u00a0 J. Fellows, T. Wirth, <em>Propellants Explos. Pyrotech.<\/em>\u00a0<strong>2026<\/strong>, <em>in press<\/em>. <span dir=\"ltr\" role=\"presentation\"><small><span style=\"font-size: 1rem\"><a href=\"https:\/\/doi.org\/10.1002\/prep.70273\">DOI<\/a><\/span><\/small><\/span><\/p>\n<h1><\/h1>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>2025 306. Hydrofluoroether Synthesis through One-Pot Anodic Iodoalkoxylation of Alkenes M. Becerra-Ruiz, B. Winterson, E. G. P\u00e9rez, T. Wirth,\u00a0Adv. Synth. Catal.\u00a02025,\u00a0367, e202401108. DOI 307. B(C6F5)3 Catalyzed Regiodivergent Thioetherifications of Alkenes via Thiiranium Intermediates: Experimental and Computational Insights N. Alotaibi, R. Babaahmadi, S. Das, E. Richards, M. Pramanik, T. Wirth, R. L. Melen, Chem. Eur. J. [&hellip;]<\/p>\n","protected":false},"author":396,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"open","template":"","meta":{"footnotes":""},"class_list":["post-10","page","type-page","status-publish","hentry"],"jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/P4Odwu-a","meta_box":[],"_links":{"self":[{"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/pages\/10","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/users\/396"}],"replies":[{"embeddable":true,"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/comments?post=10"}],"version-history":[{"count":390,"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/pages\/10\/revisions"}],"predecessor-version":[{"id":2068,"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/pages\/10\/revisions\/2068"}],"wp:attachment":[{"href":"https:\/\/blogs.cardiff.ac.uk\/wirth\/wp-json\/wp\/v2\/media?parent=10"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}